BIS[5-CHLORO-2-(PHENYLDIAZENYL-κN2)PYRIDINE-κN]BIS(THIOCYANATO-κN)IRON(II)

Bis[5-chloro-2-(phenyldiazenyl-κN2)pyridine-κN]bis(thiocyanato-κN)iron(II)

Bis[5-chloro-2-(phenyldiazenyl-κN2)pyridine-κN]bis(thiocyanato-κN)iron(II)

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In the title complex, [Fe(NCS)2(C11H8ClN3)2], the FeII atom is coordinated by two N atoms from the thiocyanate ligands and 2 Way 6.5" four N atoms from two chelating 5-chloro-2-(phenyldiazenyl)pyridine ligands, generating a fairly regular FeN6 octahedral coordination geometry.The thiocyanate ions are in a cis disposition and the pyridine N atoms are in a Custom Shaped Pillow trans orientation.In the crystal, a short intermolecular Cl.S contact [3.

366 (3) Å] is observed.

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